Piezoelectricity enhancement in graphene/polyvinylidene fluoride composites due to graphene-induced α → β crystal phase transition

نویسندگان

چکیده

Piezoelectric polymers represented by polyvinylidene fluoride (PVDF) possess many attractive attributes so they are widely used in electromechanical energy conversion devices. To further enhance the piezoelectric effect of PVDF, graphene and its derivatives have been added. A central issue is how added improves properties graphene/PVDF composites. Starting from consideration crystal phase transition α to β PVDF due addition graphene, we first introduce Cauchy’s cumulative probability function characterize evolution as a content. Then, considering relationship between dipole, microscopic dipole moment macroscopic coefficient, theory piezoelectricity for composite obtained. The shows that increases slowly at low content but increase very rapid concentration approaches percolation threshold, after which there no significant growth. coefficient also similarly until it starts drop. When 0.11 vol%, d33 22pC/N pure 39.73pC/N composite, an 80.5% d33. In addition, this extended applied other nanoparticle-enhanced polymer This model serves fill up theoretical gap enhancement graphene.

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ژورنال

عنوان ژورنال: Energy Conversion and Management

سال: 2022

ISSN: ['0196-8904', '1879-2227']

DOI: https://doi.org/10.1016/j.enconman.2022.116121